Physicochemical Characterization and Butanol Impact on Canola and Waste Cooking Oil Biodiesels: A Comparative Analysis with Binary Biodiesel Blends
DOI:
https://doi.org/10.24925/turjaf.v12i2.221-227.6569Keywords:
Canola oil, waste cooking oil, n-butanol, fuel propertiesAbstract
In this study, the physicochemical properties of canola and waste cooking oil biodiesels, as well as various binary biodiesel blends, were investigated according to TS EN 14214 and ASTM D 6751 standards. Critical parameters such as density, kinematic viscosity, cold filter plugging point (CFPP), calorific value, flash point, copper strip corrosion, water content, and ester yield were evaluated. The findings highlighted the notable density of C100 and W100 biodiesels, with the addition of butanol reducing density. While viscosity values adhered to standards, the addition of butanol was observed to decrease viscosity. CFPP values indicated compliance with standards only for C100 and C75W25. Flash points of C100 and W100 biodiesels met standards, but the addition of butanol to binary biodiesel blends lowered flash points. Copper strip corrosion values were determined to comply with standards for all fuels. Calorific values demonstrated the prominence of C100 and W100 biodiesels, with the addition of butanol observed to decrease calorific values in binary biodiesels. While water content favored canola biodiesel over waste cooking oil biodiesel, the addition of butanol to binary biodiesels increased water content. Regarding ester yield, C100 biodiesel exhibited the highest yield, and the addition of butanol to binary biodiesels increased ester yield. In conclusion, this study thoroughly analyzed the physicochemical properties of biodiesel and blend fuels, revealing the impact of butanol addition on these properties.
References
Álvarez, A., Lapuerta, M., & Agudelo, J. R. (2019). Prediction of flash point temperature of alcohol/biodiesel/diesel fuel blends. Industrial & Engineering Chemistry Research, 58(16), 6860- 6869. https://doi.org/10.1021/acs.iecr.9b00843
Atabani, A., & Silva, C. A. (2014). Calophyllum inophyllum L.– A prospective non-edible biodiesel feedstock. Study of biodiesel production, properties, fatty acid composition, blending and engine performance. Renewable and Sustainable Energy Reviews, 37, 644-655. https://doi.org/10.1016/j.rser.2014.05.037
Babu, D., Thangarasu, V., & Ramanathan, A. (2020). Artificial neural network approach on forecasting diesel engine characteristics fuelled with waste frying oil biodiesel. Applied Energy, 263, 114612. https://doi.org/10.1016/j.apenergy.2020.114612
Bhuiya, M., Rasul, M., Khan, M., & Ashwath, N. (2017). Performance and emission characteristics of binary mixture of poppy and waste cooking biodiesel. Energy Procedia, 110, 523-528. https://doi.org/10.1016/j.egypro.2017.03.179
Chhetri, A. B., Watts, K.C, & Islam, M. R. (2008). Waste Cooking Oil as an Alternate Feedstock for Biodiesel Production. Energies. https://doi.org/10.3390/en1010003
Ciubota-Rosie, C., Ruiz, J. R., Ramos, M. J., & Pérez, Á. (2013). Biodiesel from Camelina sativa: A comprehensive characterisation. Fuel, 105, 572-577. https://doi.org/10.1016/j.fuel.2012.09.062
Da Ponte, F., Vasques, R., & de Oliveira, V. (2015). Studies of second generation biodiesel formulated using binary blends of castor oil with cotton, canola and soybean oils. Eur Int J Sci Technol, 4, 195-204
Eryilmaz, T., Şahin, S., Ertuğrul, M., & Çelik, S. A. (2022). Ketencik [Camelina Sativa (L.) Crantz] Yağı Biyodizelinin ve Karışım Yakıtlarının Fizikokimyasal Özelliklerinin Araştırılması. Konya Journal of Engineering Sciences, 10(2), 287-300. https://doi.org/10.36306/konjes.1006275
Gupta, S., & Sharma. M. P. (2023). Impact of binary blends of biodiesels on fuel quality, engine performance and emission characteristics. Clean Energy, 7(2), 417-425. https://doi.org/10.1093/ce/zkad002
Haagenson, D. M., & Wiesenborn, D. P. (2011). Impact of the North Dakota Growing Location on Canola Biodiesel Quality. Journal of the American Oil Chemists Society. doi:10.1007/s11746-011-1801-4
Habibullah, M., Rizwanul, F.I., Masjuki, H., & Kalam, M. (2015). Effects of palm–coconut biodiesel blends on the performance and emission of a single-cylinder diesel engine. Energy & Fuels, 29(2), 734-743. https://doi.org/10.1021/ef502495n
Huang, Y., Li, Y., Luo, K., & Wang, J. (2020). Biodiesel/Butanol Blends as a Pure Biofuel Excluding Fossil Fuels: Effects on Diesel Engine Combustion, Performance, and Emission Characteristics. Proceedings of the Institution of Mechanical Engineers Part D Journal of Automobile Engineering. doi:10.1177/0954407020916989
Iqbal, M. A., Varman, M., Hassan, M. H., Kalam, M. A., Hossain, S., & Sayeed, I. (2015). Tailoring fuel properties using jatropha, palm and coconut biodiesel to improve CI engine performance and emission characteristics. Journal of Cleaner Production, 101, 262-270. https://doi.org/10.1016/j.jclepro.2015.04.011
Jalil, N., Lau, H.L.N., & Jalal, R.I.A. (2022). The cold flow properties of palm biodiesel for diesel blends mandate in Malaysia’s highlands. Journal of Oil Palm Research, 34(1), 116-128.
Javed, N., Tahir, M., Geng, J., Li, G., & McVetty, P. B. (2014). Identification of Brassica genotypes and molecular markers for increased seed oil content. Canadian Journal of Plant Science, 94(6), 1103-1108. https://doi.org/10.4141/cjps2013-142
Jeswani, H.K., Chilvers, A., & Azapagic, A. (2020). Environmental Sustainability of Biofuels: A Review. Proceedings of the Royal Society a Mathematical Physical and Engineering Sciences. https://doi.org/10.1098/rspa.2020.0351
Lebedevas, S., Lebedeva, G., Sendzikiene, E., & Makareviciene, V. (2010). Investigation of the performance and emission characteristics of biodiesel fuel containing butanol under the conditions of diesel engine operation. Energy & fuels, 24(8), 4503-4509. https://doi.org/10.1021/ef100505n
Meka, W., & Asere, T. G. (2022). Biodiesel Production From Waste Frying Oil Using Catalysts Derived From Waste Materials. Journal of the Turkish Chemical Society Section a Chemistry. doi:10.18596/jotcsa.997456
Nayak, S., Hoang, A., Nayak, B., & Mishra, P. (2021). Influence of fish oil and waste cooking oil as post mixed binary biodiesel blends on performance improvement and emission reduction in diesel engine. Fuel, 289, 119948. https://doi.org/10.1016/j.fuel.2020.119948
Nita, I., Geacai, S., & Iulian, O. (2011). Measurements and correlations of physico-chemical properties to composition of pseudobinary mixtures with biodiesel. Renewable Energy, 36(12), 3417-3423. https://doi.org/10.1016/j.renene.2011.05.020
Odega, C., Anguruwa, G., & Fakorede, C. (2021). Biodiesel Production and Characterization from Used Vegetable Oil. Journal of Applied Sciences and Environmental Management, 25(4), 537-542. 10.4314/jasem.v25i4.7
Oğuz, H., Öğüt, H., Aydın, F., Ciniviz, M., & Eryılmaz, T. (2019). Investigation of engine performance and kit design for the usage of safflower oil as in diesel engine. Renewable Energy, 143, 692-702. https://doi.org/10.1016/j.renene.2019.04.142
Ong, H., Silitonga, A., Masjuki, H., Mahlia, T., Chong, W., & Boosroh, M. (2013). Production and comparative fuel properties of biodiesel from non-edible oils: Jatropha curcas, Sterculia foetida and Ceiba pentandra. Energy conversion and Management, 73, 245-255. Doi:10.1016/j.enconman.2013.04.011
Öğüt, H., Akınerdem, F., Pehlivan, E., Aydın, M. E., & Oğuz H. (2004). Investigation of biodiesel production processes from some oil crops in Turkey and its use in diesel engines in terms of agriculture, environment, food, chemistry and technological aspects :DPT Project No:2004/7 Bioenergy 2004 Symposium, Izmir.
Örs, İ., Sarıkoç, S., Atabani, A., & Ünalan, S. (2019). Experimental investigation of effects on performance, emissions and combustion parameters of biodiesel–diesel–butanol blends in a direct-injection CI engine. Biofuels. https://doi.org/10.1080/17597269.2019.1608682
Öztürk, E. (2015). Performance, emissions, combustion and injection characteristics of a diesel engine fuelled with canola oil–hazelnut soapstock biodiesel mixture. Fuel Processing Technology, 129, 183-191. https://doi.org/10.1016/j.fuproc.2014.09.016
Panwar, N.L., Kaushik, S.C., & Kothari, S. (2011). Role of Renewable Energy Sources in Environmental Protection: A Review. Renewable and Sustainable Energy Reviews. doi:10.1016/j.rser.2010.11.037
Ramuhaheli, S., Veeredhi, V., & Enweremadu, C. (2022). The Performance and Emission Characteristics Assessment of Hybrid Biodiesel/Ethanol Blends in a Diesel Engine. Environmental and Climate Technologies, 26(1), 670-683. https://doi.org/10.2478/rtuect-2022-0051
Roy, M. M., Alawi, M., & Wang, W. (2013). Effects of canola biodiesel on a DI diesel engine performance and emissions. International Journal of Mechatronics Engineering IJMMEIJENS, 13(02), 46-53
Sharma, R., Somidi, A.K.R., & Dalai, A.K. (2015). Preparation and Properties Evaluation of Biolubricants Derived From Canola Oil and Canola Biodiesel. Journal of Agricultural and Food Chemistry. doi:10.1021/jf505825k
Silitonga, A., Masjuki, H., Mahlia, T., Ong, H., Chong, W., & Boosroh, M. (2013). Overview properties of biodiesel diesel blends from edible and non-edible feedstock. Renewable and sustainable energy reviews, 22, 346-360. https://doi.org/10.1016/j.rser.2013.01.055
Singh, N., Agarwal, P., & Porwal, SK. (2022). Natural antioxidant extracted waste cooking oil as sustainable biolubricant formulation in tribological and rheological applications. Waste and Biomass Valorization, 13(7), 3127-3137. https://doi.org/10.1007/s12649-022-01745-6
Singh, P., Chauhan, S., Goel, V., & Gupta, A.K. (2020). Enhancing diesel engine performance and reducing emissions using binary biodiesel fuel blend. Journal of Energy Resources Technology, 142(1), 012201. https://doi.org/10.1115/1.4044058
Sirviö, K., Niemi, S., Heikkilä, S., Kiijärvi, J., Hissa, M., & Hiltunen, E. (2019). Feasibility of new liquid fuel blends for medium-speed engines. Energies, 12(14), 2799. https://doi.org/10.3390/en12142799
Souissi, Y., Alouini, M., & Mnif, W. (2018). Chemical and Biological Investigation of Organic Wastes of Frying Oils and Beef Fats: Valorization for Biodiesel Production. Journal of Chemistry, 2018, 1-9. doi:10.1155/2018/6248047
Şahin, S., & Mengeş, H.O. (2022). Determination of the Effects of Some Additives Added to the Mixture of Diesel and Safflower Biodiesel on Exhaust Emissions. Journal of Tekirdag Faculty of Agriculture, 19(4), 769-787. https://doi.org/10.33462/jotaf.1075550
Sanli, H., Canakci, M., & Alptekin, E. (2011) Characterization of waste frying oils obtained from different facilities. In World Renewable Energy Congress-Sweden (Vol. 57, pp. 8-13). Linköping University Electronic Press Linköping; Sweden.
Taib, N. M., Zainuddin, M. S., Mansor, M. R. A., & Ilham, Z. (2018). Performance and emission opacity of canola and soybean biodiesel fuel in a diesel engine. JOurnal of Mechanical Engineering and Sciences, 12(2), 3689. doi:10.15282/jmes.12.2.2018.14.0326
Vaka, M., Walvekar, R., Rasheed, A.K., & Khalid M. (2020). A Review on Malaysia’s Solar Energy Pathway Towards Carbon Neutral Malaysia Beyond Covid’19 Pandemic. Journal of Cleaner Production. doi:10.1016/j.jclepro.2020.122834
Yeşilyurt, M., Arslan, M., & Eryilmaz, T. (2018). Experimental Investigation of The Effects of Ethanol Addition Into Biodiesel-Diesel Fuel Blends on The Performance, Combustion and Emission Characteristics . J. of Thermal Science and Technology, 38(2), 129-150.
Zori, S. G., Bakker, M. H., Tuokuu, F. X. D., & Pare, J. (2022). Market reaction to fossil fuel divestment announcements: Evidence from the United States. Business and Society Review, 127(4), 939-960. doi:10.1111/basr.12295
Zubenko, S.O., Konovalov, S.V., Denysiuk, B.A., & Patrylak, L. K. (2021). Alkaline synthesis of fatty acids iso-propyl esters. Catalysis and petrochemistry, (32), 32-39. doi:10.15407/kataliz2021.32.032
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